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371.
Ikurou Umezu Muneyuki Naito Daisuke Kawabe Yusuke Koshiba Katsuki Nagao Akira Sugimura Tamao Aoki Mitsuru Inada Tadashi Saitoh Atsushi Kohno 《Applied Physics A: Materials Science & Processing》2014,117(1):155-159
Hyperdoping with deep-level impurity is a promising method to prepare intermediate band semiconductors. We prepared silicon hyperdoped with deep-level impurities, sulfur and titanium, by ion implantation followed by pulsed YAG laser melting. The processes of sulfur and titanium hyperdoping are comparatively studied. The amorphous sulfur and titanium ion-implanted layers changed to monocrystal by following pulsed laser melting. The depth profile of sulfur impurity after pulsed laser melting is similar to that of ion-implanted sample, while large segregation is observed for titanium hyperdoping. The crystallinity and degree of segregation depend on the laser shot number and initially implanted titanium dose. There is a trade-off between crystallinity and depth profile of impurity for titanium hyperdoping. From a viewpoint material processing, formation of high-quality silicon monocrystal hyperdoped with sulfur is easier than that with titanium. Correlation between the mid-infrared optical absorption and photoconductivity is also discussed for sulfur-hyperdoped sample. 相似文献
372.
Makoto Oba Naomi Kawabe Hiroomi Takazaki Yosuke Demizu Mitsunobu Doi Masaaki Kurihara Hiroshi Suemune Masakazu Tanaka 《Tetrahedron》2014
The chiral cyclic α,α-disubstituted α-amino acid, (3R,4R)-1-amino-3,4-diazido-1-cyclopentanecarboxylic acid [(R,R)-Ac5cdN3], was introduced into achiral α-aminoisobutyric acid (Aib) peptides. The azido groups of (R,R)-Ac5cdN3 in the peptides were efficiently converted into 1,2,3-triazole functional groups. FTIR, 1H NMR, and CD spectra revealed that the dominant conformations of all peptides in solution were 310-helical structures without controlling the helical-screw sense. X-ray crystallographic analyses of peptides containing (R,R)-Ac5cdN3 showed that both the right-handed (P) and left-handed (M) 310-helical structures were present in the crystal state. 相似文献
373.
Let K denote a field and let V denote a vector space over K with finite positive dimension.We consider a pair of K-linear transformations A:V→V and A∗:V→V that satisfy the following conditions: (i) each of A,A∗ is diagonalizable; (ii) there exists an ordering of the eigenspaces of A such that A∗Vi⊆Vi-1+Vi+Vi+1 for 0?i?d, where V-1=0 and Vd+1=0; (iii) there exists an ordering of the eigenspaces of A∗ such that for 0?i?δ, where and ; (iv) there is no subspace W of V such that AW⊆W,A∗W⊆W,W≠0,W≠V.We call such a pair a tridiagonal pair on V. It is known that d=δ and for 0?i?d the dimensions of coincide.In this paper we show that the following (i)-(iv) hold provided that K is algebraically closed: (i) Each of has dimension 1.(ii) There exists a nondegenerate symmetric bilinear form 〈,〉 on V such that 〈Au,v〉=〈u,Av〉 and 〈A∗u,v〉=〈u,A∗v〉 for all u,v∈V.(iii) There exists a unique anti-automorphism of End(V) that fixes each of A,A∗.(iv) The pair A,A∗ is determined up to isomorphism by the data , where θi (resp.) is the eigenvalue of A (resp.A∗) on Vi (resp.), and is the split sequence of A,A∗ corresponding to and . 相似文献
374.
The reactivity of 5,6-dihydroxyindole and its major dimers has been studied with the use of a recently proposed general-purpose reactive indicator (Anderson et al. J. Chem. Theory Comput. 2007, 3, 358-374) from ab initio density-functional theory calculations. Theoretical prediction has reasonably explained previously isolated oligomers up to tetramers. The oxidative polymerization is governed by the electron-transfer-controlled reaction. The electrostatic interaction plays a regioselective role in the reactant complex and/or intermediates. A monomer-dimer coupling is able to form trimers, while a part of it is prevented by the exchange repulsion, i.e., steric hindrance. Therefore, a dimer-dimer coupling is also able to form tetramers. 相似文献
375.
Toganoh M Gokulnath S Kawabe Y Furuta H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(14):4380-4391
A series of 5,10,15-tris(pentafluorophenyl) doubly N-confused bilanes were synthesized in a stepwise manner with the aid of sterically demanding N-protecting groups, in which the difference in reactivity between regular pyrrole and N-confused pyrrole plays a crucial role in the synthetic strategy. Some doubly N-confused bilanes were converted into porphyrinoids or a unique 2:2 copper(II) complex with a helical structure. In addition, the conformations and electronic states of the doubly N-confused bilanes were investigated theoretically, giving fruitful information about the effect of confusion on the bilane skeleton. 相似文献
376.
Funabiki K Mase H Saito Y Otsuka A Hibino A Tanaka N Miura H Himori Y Yoshida T Kubota Y Matsui M 《Organic letters》2012,14(5):1246-1249
Novel near-infrared (NIR)-sensitizing (up to 800 nm) simple asymmetric squaraine dyes (Sq 31 and Sq 33) carrying indoline moieties that did not require the introduction of any linker groups were developed. DSSCs fabricated with Sq 33 exhibited remarkable characteristics in the long-wavelength visible and NIR region (up to 800 nm), such as a conversion efficiency of 3.75% (AM 1.5G) with an incident photon-to-current conversion efficiency of 63% (650 nm), a short-circuit photocurrent density of 13.64 mA, an open-circuit photovoltage of 0.48, and a fill factor of 0.57. 相似文献
377.
M Tamaki T Harada K Fujinuma K Takanashi M Shindo M Kimura Y Uchida 《Chemical & pharmaceutical bulletin》2012,60(9):1134-1138
The substitution of each constituent amino acid residue of gramicidin S (GS), cyclo(-Val(1,1')-Orn(2,2')-Leu(3,3')-D-Phe(4,4')-Pro(5,5')-)(2) with Lys residue indicated that each side chain structure of the constituent amino acid residues affect largely the antibiotic activity and hemolytic activity of GS. Further, the substitution of D-Phe(4,4') and Pro(5,5') residues with basic amino acid residues as a Lys residue results the high antibiotic activity and the very low hemolytic activity. Thus, we have found novel positions on the scaffold of GS at D-Phe(4,4') and Pro(5,5') residues whose modification will significantly increase the therapeutic index. 相似文献
378.
The CCSD(T) level interaction energies of eight orientations of nitrobenzene-benzene complexes and nine orientations of nitrobenzene dimers at the basis set limit have been estimated. The calculated interaction energy of the most stable slipped-parallel (C(s)) nitrobenzene-benzene complex was -4.51 kcal/mol. That of the most stable slipped-parallel (antiparallel) (C(2h)) nitrobenzene dimer was -6.81 kcal/mol. The interaction energies of these complexes are significantly larger than that of the benzene dimer. The T-shaped complexes are substantially less stable. Although nitrobenzene has a polar nitro group, electrostatic interaction is always considerably weaker than the dispersion interaction. The dispersion interaction in these complexes is larger than that in the benzene dimer, which is the cause of the preference of the slipped-parallel orientation in these complexes. 相似文献
379.
Masaki Matsui Yoshinori Asamura Kazumasa Funabiki Tsukasa Yoshida 《Tetrahedron》2010,66(37):7405-1642
Substituited triple rhodanine indoline dyes showed higher performance than known triple rhodanine derivative (D150). A few triple rhodanine indoline derivatives showed comparable conversion efficiency to D149. 相似文献
380.
A new universality class of quantum criticality emerging in itinerant electron systems with strong local electron correlations is discussed. The quantum criticality of a Ce- or Yb-valence transition gives us a unified explanation for unconventional criticality commonly observed in heavy fermion metals such as YbRh(2)Si(2), β-YbAlB(4), YbCu(5-x)Al(x), and CeIrIn(5). The key origin is due to the locality of the critical valence fluctuation mode emerging near the quantum critical end point of the first-order valence transition, which is caused by strong electron correlations for f electrons. The wider relevance of this new criticality and important future measurements to uncover its origin are also discussed. 相似文献